New silver BioMOFs driven by 1,3,5-triaza-7-phosphaadamantane-7-sulfide (PTAS): synthesis, topological analysis and antimicrobial activity
Sabina W. Jaros , Piotr Smoleński , Fatima C. Guedes da Silva , Magdalena Florek , Jarosław Król , Zdzisław Staroniewicz , Armando J L Pombeiro , Alexander M. Kirillov
AbstractTwo new bioactive silver-organic frameworks [Ag(μ 3 -PTAS)] n (NO 3 ) n ·nH 2 O (1) and [Ag 4 (μ 4 -PTAS)(μ 5 -PTAS)(μ 2 - SO 4 ) 2 (H 2 O) 2 ] n · 2nH 2 O (2) were easily assembled, thus opening up the application of PTAS as a versatile N,S-building block in the crystal engineering of MOFs. The obtained products reveal infinite 3D networks driven by multiply bridging PTAS spacers that adopt unprecedented N 2 S-coordination modes. The topological analysis of 1 discloses an uninodal 3-connected net with the srs (SrSi 2 ) topology, whereas 2 features a pentanodal 3,4,5-connected net with a hitherto undocumented topology. Apart from representing the first MOFs derived from PTAS, the compounds 1 and 2 display notable antibacterial and antifungal activities. © 2013 The Royal Society of Chemistry.
|Journal series||CrystEngComm, ISSN 1466-8033, (A 35 pkt)|
|Publication size in sheets||0.5|
|ASJC Classification||; ;|
|Score|| = 35.0, 01-06-2020, ArticleFromJournal|
= 35.0, 01-06-2020, ArticleFromJournal
|Publication indicators||= 39; = 36; : 2013 = 1.102; : 2013 = 3.858 (2) - 2013=3.908 (5)|
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